John Breker

AGVISE Demonstration Project: Lowering Soil pH with Elemental Sulfur

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This article originally appeared in the AGVISE Laboratories Spring 2025 Newsletter.

There may not be silly questions, but there are silly answers. Every so often, we get questions about unusual solutions to manage calcareous soils in the northern Great Plains and Canadian Prairies. The most frequent oddball “solutions” involve lowering soil pH with elemental sulfur on calcareous soils. Such suggestions might work on acidic soils; however, the dominant calcareous soils in the region have high pH (>7.3) and tons of natural calcium carbonate that make such attempts impractical and expensive. To put the nail in the coffin, AGVISE Laboratories started some long-term demonstration projects to show plainly why such ideas do not work or may cost way too much!

If possible, we’d like an easy and cheap solution to lower soil pH, like applying only 100 to 200 lb/acre elemental sulfur (S). In soil, elemental S oxidizes to sulfuric acid, which can lower soil pH. However, the large amount of calcium carbonate (free lime) keeps our soils buffered at high pH. To lower soil pH permanently, you must first react and neutralize the carbonate with elemental S before the soil pH can budge. With 100 lb/acre elemental S applied each year, that does not sound too difficult, right?

Elemental sulfur project with rates ranging from 0 to 40,000 lb/acre elemental sulfur. Can you identify the 20 ton/acre rate?

Not so fast. A soil with only 1% calcium carbonate equivalent (CCE) takes 3.2 ton/acre elemental S (6,400 lb/acre) to neutralize the carbonate alone in the 0-6 inch soil depth. In 2020, we started an elemental S project at Northwood, ND on soil containing 4.5% CCE, which would require literal tons of elemental S to lower soil pH. A previous project started in 2005 had used 10,000 lb/acre elemental S, but it was not enough to lower soil pH beyond pH 7.8 after 15 years. This time, we decided to get serious and use elemental S rates from 0 to 40,000 lb/acre (Figure 1). The elemental S rates were intended to hit above and below the target 30,000 lb/acre elemental S rate required to react and neutralize 4.5% CCE.

For the first three years of the project, we saw little to no change in soil pH, regardless of elemental S rate. The oxidation process that converts elemental S to sulfuric acid is a slow, biological process that can take a long time. In Fall 2024, we finally saw real changes in soil pH following elemental S application. The 16,000 lb/acre elemental sulfur rate reached pH 7.5. The 24,000 lb/acre elemental sulfur rate reached pH 7.0. The 40,000 lb/acre elemental sulfur rate reached pH 6.0, a dramatic change! The lowest 8,000 lb/acre elemental sulfur rate, however, was no different than the control.

There is still some unoxidized elemental sulfur and unreacted calcium carbonate in the soil, and we will continue to monitor these long-term demonstration plots in future years. The project demonstrates that elemental sulfur can lower soil pH, but it also shows that the very high amounts of elemental sulfur required are both impractical and expensive. A few hundred pounds of elemental sulfur applied each year will get you nowhere. In contrast, the very high elemental sulfur rates will break the bank. This is why we consider such “solutions” as either ineffective attempts or downright silly wastes.

John Lee

Adjusting high soil pH with elemental sulfur

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Soil pH is a soil chemical property that measures soil acidity or alkalinity, and it affects many soil chemical and biological activities. Soils with high pH can reduce the availability of certain nutrients, such as phosphorus and zinc. Soils of the northern Great Plains and Canadian Prairies often have high soil pH (>7.3) and contain calcium carbonate (free lime) at or near the soil surface. It is the calcium carbonate in soil that maintains high soil pH and keeps it buffered around pH 8.0. The calcium carbonate originates from soil formation processes since the latest glacial period.

An unfounded soil management suggestion is that soil pH can be successfully reduced by applying moderate rates of elemental sulfur (about 100 to 200 lb/acre elemental S). Elemental sulfur must go through a transformation process called oxidation, converting elemental sulfur (S0) to sulfuric acid (H2SO4), a strong acid. Sulfuric acid does lower soil pH, but the problem is the amount of carbonate in the northern region, which commonly ranges from 1 to 5% CCE and sometimes over 10% CCE. Soils containing carbonate (pH >7.3) will require A LOT of elemental sulfur to neutralize carbonate before it can reduce soil pH.

To lower pH in soils containing carbonate, the naturally-occurring carbonate must first be neutralized by sulfuric acid generated from elemental sulfur. You can visualize the fizz that takes place when you pour acid on a soil with carbonate. That fizz is the acid reacting with calcium carbonate to produce carbon dioxide (CO2) gas. Once all calcium carbonate in soil has been neutralized by sulfuric acid, only then can the soil pH be lowered permanently. It is important to note that sulfate-sulfur sources, such as gypsum (calcium sulfate, CaSO4), do not create sulfuric acid when they react with soil, so they cannot neutralize calcium carbonate or change soil pH (Figure 1).

Figure 1. Soil pH following gypsum application on soil with high pH and calcium carbonate.

In 2005, AGVISE Laboratories installed a long-term demonstration project evaluating elemental sulfur and gypsum on a soil with pH 8.0 and 2.5% calcium carbonate equivalent (CCE). The highest elemental sulfur rate was 10,000 lb/acre (yes, 5 ton/acre)! We chose such a high rate because the soil would require a lot of elemental sulfur to neutralize all calcium carbonate. Good science tells us that 10,000 lb/acre elemental sulfur should decrease soil pH temporarily, but it is still not enough to lower soil pH permanently. In fact, this is exactly what we saw (Figure 2). Soil pH declined in the first year, but it returned to the initial pH over subsequent years because the amount of elemental sulfur was not enough to neutralize all calcium carbonate.

Figure 2. Soil pH following elemental sulfur application on soil with high pH and calcium carbonate.

A quick calculation showed that the soil with 2.5% CCE would require about 16,000 lb/acre elemental sulfur to neutralize all calcium carbonate in the topsoil. Such high rates of elemental sulfur are both impractical and expensive on soils in the northern Great Plains. The only thing to gained is a large bill for elemental sulfur. While high soil pH does lower availability of phosphorus and zinc, you can overcome these limitations with banded phosphorus fertilizer and chelated zinc on sensitive crops. All in all, high soil pH is manageable with the appropriate strategy. That strategy does not involve elemental sulfur.

Richard Jenny

Fertilizing soybean

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Soybean acres expanded greatly across the northern Great Plains and into Manitoba through the 1990s and 2000s. Today, soybean occupies a large portion of planted acres and makes a desirable rotation crop in canola, corn, and small grain production systems. As soybean has advanced northward and westward, soybean is often billed as a low maintenance crop, requiring no fertilizer or even seed inoculation. The fact is, if you expect soybean to be a low maintenance crop, you can expect low yield results. Achieving high soybean yields starts with a good, long-term soil fertility plan.

Nitrogen

Soybean yielding 40 bu/acre requires about 200 lb/acre nitrogen, but luckily you do not have to provide all the nitrogen! Soybean relies on nitrogen-fixing bacteria to meet its nitrogen requirements. Legumes, like soybean, form a symbiotic relationship with N-fixing bacteria, housed in root nodules, to provide sufficient nitrogen. Each legume species requires a unique N-fixing bacterium, thus an inoculant for lentil or pea does not work on soybean. Soybean seed must be inoculated with the N-fixing bacteria Bradyrhizobia japonicum. Ensure you have the proper soybean-specific seed inoculant. You can count the number of nodules on soybean roots and verify the presence of active N-fixing bacteria in the nodules with bright pink centers. These soybean plants have enough active N-fixing bacteria to meet soybean nitrogen requirements.

For new soybean growers, the N-fixing bacteria Bradyrhizobia japonicum is not naturally present in soil and seed inoculation is required. During the first few years of soybean establishment, supplemental nitrogen may be required to achieve good soybean yield while the N-fixing bacteria population builds. University of Minnesota researchers in the northern Red River Valley showed that soils with less than 75 lb/acre nitrate-N (0-24 inch) required 40-50 lb/acre additional preplant nitrogen. If successful inoculation and good nodule counts are observed in the first year, then no additional nitrogen should be required in subsequent years.

Plant soybean on soils with less than 100 lb/acre nitrate-N (0-24 inch), if possible. High residual soil nitrate may delay root nodulation with N-fixing bacteria and increase the severity of iron deficiency chlorosis (IDC). Because soybean can fix its own nitrogen, you may recoup better economic return on soils with high residual nitrate with crops that do not fix their own nitrogen like corn or wheat.

Phosphorus

Soybean does not respond to phosphorus as dramatically as grass crops like corn or wheat do. Nevertheless, medium to high soil test P are required to achieve good soybean yields. Soybean responds to broadcast P placement better than seed-placed or sideband P. In dryland regions where soybean is planted with air drills, seed-placed P or sideband P is often the only opportunity to apply phosphorus. You must pay special attention to seed-placed fertilizer safety with soybean. An air drill with narrow row spacing (6 inch) should not exceed 20 lb/acre P2O5 (40 lb/acre monoammonium phosphate, MAP, 11-52-0). Fertilizer rates exceeding the seed safety limit may delay seedling emergence and reduce plant population. For wider row spacings, no fertilizer should be placed with seed.

Potassium

Soybean removes far more potassium in harvested seed than canola or wheat. Soybean yielding 40 bu/acre removes about 60 lb/acre K2O, while wheat yielding 60 bu/acre removes only 20 lb/acre K2O. Pay close attention to potassium removal across the crop rotation. After soybean is added to the crop rotation, cumulative potassium removal greatly increases, and declining soil test K is observed over time.

Do not place potassium with soybean seed; delayed seedling emergence and reduced plant population can occur. Any potassium fertilizer should be broadcasted or banded away from seed.

Sulfur

Sulfur deficiency in soybean is uncommon, yet sometimes observed on coarse-textured soils with low organic matter (< 3.0%). Soybean response to sulfur is usually confined to certain zones within fields. With additional sulfur, soybean can produce more vegetative growth, but more vegetative growth may increase soybean disease severity, such as white mold. The residual sulfur remaining after sulfur-fertilized canola, corn, or small grain is often sufficient to meet soybean sulfur requirements.

Iron

Soybean is very susceptible to iron deficiency chlorosis (IDC). Soybean IDC is not caused by low soil iron but instead by soil conditions that decrease iron uptake by soybean roots. Soybean IDC risk and severity are primarily related to soil carbonate content (calcium carbonate equivalent, CCE) and worsened by salinity (electrical conductivity, EC).

Soybean IDC is common in the upper Midwest, northern Great Plains, and Canadian Prairies, where soils frequently have high carbonate and/or salinity. Within a field, IDC symptoms are usually confined to soybean IDC hotspots with high carbonate and salinity; however, symptoms may appear across a field if high carbonate and salinity are present throughout the field. Soybean IDC severity is made worse in cool, wet soils and soils with high residual nitrate. Soil pH is not a good indicator of soybean IDC risk because some high pH soils lack high carbonate and salinity, which are the two principal risk factors.

Guidelines for managing soybean IDC:

  1. Soil test each field, zone, or grid for soil carbonate and salinity. This may require soil sampling prior to soybean (possibly outside of your usual soil sampling rotation) or consulting previous soil sampling records.
  2. Plant soybean in fields with low carbonate and salinity (principal soybean IDC risk factors).
  3. Choose an IDC tolerant soybean variety on fields with moderate to high carbonate and salinity. This is your most practical option to reduce soybean IDC risk. Consult seed dealers, university soybean IDC ratings, and neighbor experiences when searching for IDC tolerant soybean varieties.
  4. Plant soybean in wider rows. Soybean IDC tends to be less severe in wide-row spacings (more plants per row, plants are closer together) than narrow-row spacings or solid-seeded spacings.
  5. Apply chelated iron fertilizer (e.g., high quality FeEDDHA) in-furrow at planting. In-furrow FeEDDHA application may not be enough to help an IDC susceptible variety in high IDC risk soils (see points #2 and #3).
  6. Avoid planting soybean on soils with very high IDC risk.

Zinc

Zinc deficiency in soybean is rare, even on soils with low soil test Zn. Soybean seed yield response to zinc is limited on soils with less than 0.5 ppm Zn. More zinc sensitive crops like corn, dry bean, flax, and potato will respond to zinc on soils with less than 1.0 ppm Zn. If zinc sensitive crops also exist in the crop rotation, you may apply zinc with broadcast phosphorus or potassium during the soybean year as another opportunity to build soil test Zn across the crop rotation.

John Lee

Caution: Ammonium Sulfate with Seed

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Seed-placed fertilizer is a common practice to increase seedling vigor and optimize fertilizer placement and crop response. This is a popular strategy to apply phosphorus for canola, corn, and wheat. However, the seed-placed fertilizer rate cannot exceed seed safety limits, otherwise seedling germination and plant population may be reduced. Sulfur is very important in canola growth and development, so farmers often try placing ammonium sulfate (AMS) with canola seed as well! This can create big problems.

A team of agronomists and soil scientists at the University of Manitoba conducted greenhouse and field studies, examining the effect of seed-placed ammonium sulfate on canola plant population and seed yield. The plant population loss was much greater on soils with pH > 7.5 (Figure 1). The high pH soils contained calcium carbonate (CaCO3), which reacts with ammonium sulfate to create calcium sulfate (gypsum) and ammonium carbonate. The higher reaction pH of ammonium carbonate produces free ammonia (NH3). Free ammonia (NH3) in soil is toxic to living organisms and kills germinating seeds. Acute ammonia toxicity is a major concern with fertilizer materials that liberate free ammonia (NH3) in soil, such as anhydrous ammonia (82-0-0) or urea (46-0-0), ultimately reducing plant population if you are not careful with fertilizer rate and placement.

For Caution: Ammonium Sulfate with Seed post

Figure 1. Ammonium sulfate (AMS, 21-0-0-24S) included with seed-placed monoammonium phosphate (MAP, 10-52-0) reduced canola plant population. Soil carbonate content is 21% CCE and 0.5% CCE in knoll soil and hollow soil, respectively. Brandon, Manitoba.

Across the landscape, soil pH and carbonate content will vary. The well-drained lower landscape positions (swales, hollows) often have acidic to neutral pH and little carbonate. The upper landscape positions (knobs, knolls), suffering decades of soil erosion, often have high pH and ample carbonate (Figure 1). The risk of plant population loss is greater on eroded knobs where adding ammonium sulfate can create ammonia toxicity concern.

Considerable yield loss will occur if canola plant population is less than 70 plants per square meter. Even with low fertilizer rates, the interaction of seed-placed ammonium sulfate and phosphorus can greatly reduce canola plant population. In Manitoba, 25% plant population loss was observed with only 8 lb/acre S and 18 lb/acre P2O5 (Figure 2).For Caution: Ammonium Sulfate with Seed article

Figure 2. Ammonium sulfate (AMS, 21-0-0-24S) included with seed-placed monoammonium phosphate (MAP, 10-52-0) reduced canola plant population. Carman, Manitoba, 2011.

Sulfur is vital for successful canola production, but it must be applied safely. There are new air drill configurations with innovative seed and fertilizer placement options. Seed safety is paramount with seed-placed fertilizer. Ammonium sulfate should be broadcasted or banded away from seed (mid-row). Keeping ammonium sulfate away from seed will also allow you to maximize seed-placed phosphorus rates and efficiency without jeopardizing seed safety.

Placing ammonium sulfate with seed should be an emergency option only. Canola plant population loss should be expected, even at low ammonium sulfate rates, on soils with pH greater than 7.5 and calcium carbonate.